Unraveling the characteristics of dissolved organic matter removed by aluminum species based on FT-ICR MS analysis.

Given the complexity of dissolved organic matter (DOM) and its interactions with coagulant chemicals, the mechanisms of DOM removal by aluminum (Al) coagulants remains a significant unknown. In this study, six test waters containing DOM with molecular weight (MW, <1 kDa, 1-10 kDa and >10 kDa) and hydrophobicity (hydrophilic, transphilic and hydrophobic) were prepared and coagulated with Al0, Al13 and Al30. The molecular-level characteristics of DOM molecules that were removed or resistant to removal by Al species were analyzed using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). The results showed that at the molecular level, saturated and reduced tannins and lignin-like compounds containing abundant carboxyl groups exhibited higher coagulation efficiency. Unsaturated and oxidized lipids, protein-like, and carbohydrates compounds were relatively resistant to Al coagulation due to their higher polarity and lower content of carboxyl groups. Al13 removed molecules across a wider range of molecular weights than Al0 and Al30, thus the DOC removal efficiency of Al13 was the highest. This study furthers the understanding of interactions between Al species and DOM, and provides scientific insights on the operation of water treatment plants to improve control of DOM.

PFAS promotes disinfection byproduct formation through triggering particle-bound organic matter release in drinking water pipes.

Loose deposit particles in drinking water distribution system commonly exist as mixtures of metal oxides, organic materials, bacteria, and extracellular secretions. In addition to their turbidity-causing effects, the hazards of such particles in drinking water are rarely recognized. In this study, we found that trace per- and polyfluoroalkyl substances (PFASs) could dramatically promote the formation of disinfection byproducts (DBPs) by triggering the release of particle-bound organic matter. Carboxylic PFASs have a greater ability to increase chloroacetic acid than sulfonic PFASs, and PFASs with longer chains have a greater ability to increase trichloromethane release than shorter-chain PFASs. Characterization by organic carbon and organic nitrogen detectors and Fourier transform ion cyclotron resonance mass spectrometry revealed that the released organic matter was mainly composed of proteins, carbohydrates, lignin, and condensed aromatic structures, which are the main precursors for the formation of DBPs, particularly highly toxic aromatic DBPs. After the release of organic matter, the particles exhibit a decrease in surface functional groups, an increase in surface roughness, and a decrease in particle size. The findings provide new insights into the risks of loose deposits and PFASs in drinking water, not only on PFASs per se but also on its effect of increasing toxic DBPs.

Manganese and iron oxides on pipe surface promote dissolved aluminum accumulation in drinking water distribution systems.

Aluminum-containing deposits are pervasive in drinking water distribution systems (DWDSs). However, the mechanisms driving dissolved Al transformation to pipe deposits remain elusive. This study investigated dissolved Al accumulation in DWDSs by batch experiments and long-term pipe experiments using actual finished water. PVC pipe experiments showed that dissolved Al hardly deposited on clean PVC pipe walls at alkaline pH. However, it could be substantially anchored by the pipe surface covered with Mn and Fe deposits formed from Mn(II) oxidation and Fe(III) precipitation. Batch experiments verified that the synthesized Mn and Fe oxides exhibited a strong capacity for dissolved Al uptake at pH 7.7 and 9.0 (dissolved Al was the dominant form). Biofilms on pipe walls also enhanced dissolved Al accumulation. Iron pipe experiments showed that corroded iron pipes with abundant iron corrosion products readily accumulated Al. Compared to chlorination and chloramination, non-disinfected conditions were more favorable for particulate Al deposition on iron pipe surface, probably due to Al immobilization by biofilms. In addition, continuous Al accumulation in iron pipes enhanced Fe release to pipe water. This study highlighted the important role of metal oxides in dissolved Al accumulation in DWDSs with abundant Mn and Fe solids, which provided new insights into deposit formation and control strategies.

Reduced formation of brominated trihalomethanes during chlorination of bromide-containing waters in the presence of Mn(II).

Manganese(II) (Mn(II)) and bromide (Br-) are common in natural waters. This study investigated the effect of in-situ Mn(II) oxidation and preformed MnOx on the brominated trihalomethane (Br-THM) formation during chlorination of bromide-containing waters. The results showed Br-THM formation could be substantially inhibited by in-situ Mn(II) oxidation, but the addition of preformed MnOx had limited influence on Br-THM formation during chlorination of bromide-containing waters. Analysis of bromine species showed that about 30 % bromine species were incorporated into the MnOx particles and formed MnOx-Br during the in-situ Mn(II) oxidation process. Consequently, the availability of reactive bromine species for the reaction with dissolved organic matter (DOM) reduced, leading to less Br-THM formation. X-ray diffraction (XRD) analysis of in-situ Mn(II) oxidation product indicated the presence of Br- decreased the crystallinity of Mn oxides, verifying the bromine species entered MnOx crystal. However, the adsorptive uptake of bromine species by preformed MnOx was negligible and had no impact on Br-THM formation. Inhibition rate of Mn(II) oxidation on THM formation decreased with increasing specific ultraviolet absorbance (SUVA254) value of filtered water, showing SUVA254 could be a good indicator of DOM competition ability for oxidant with Mn(II). In addition, Excitation/Emission Matrix indicated that Mn(II) could form complexes with humic substances, which might also retard the reaction between humic substances and oxidant to form Br-THMs. This study highlighted the inhibiting effect of in-situ Mn(II) oxidation on Br-THM formation during chlorination of bromide-containing waters.

Metabolic response of bacterial community to sodium hypochlorite and ammonia nitrogen affected the antibiotic resistance genes in pipelines biofilm.

The biofilm is important for the antibiotic resistance genes (ARGs) propagation in drinking water pipelines. This study investigated the influence of chlorine disinfection and ammonia nitrogen on the ARGs in pipelines biofilm using metagenomic and metabolomics analysis. Chlorine disinfection reduced the relative abundance of unclassified_c_Actinobacteria, Acidimicrobium, and Candidatus_Pelagibacter to 394-430 TPM, 114-123 TPM, and 49-54 TPM, respectively. Correspondingly, the ARGs Saur_rpoC_DAP, macB, and mfd was reduced to 8-12 TPM, 81-92 TPM and 30-35 TPM, respectively. The results of metabolomics suggested that chlorine disinfection suppressed the pathways of ABC transporters, fatty acid biosynthesis, biosynthesis of unsaturated fatty acids, and biosynthesis of amino acids. These pathways were related to the cell membrane integrality and extracellular polymeric substances (EPS) secretion. Chlorine disinfection induced the decrease of EPS-related genes, resulting in the lower relative abundance of bacterial community and their antibiotic resistance. However, added approximately 0.5 mg/L NH3-N induced up-regulation of these metabolic pathways. In addition, NH3-N addition increased the relative abundance of enzymes related to inorganic and organic nitrogen metabolic pathway significantly, such as ammonia monooxygenase, glutamine synthetase, and glutamate synthase. Due to the EPS protection and nitrogen metabolism, the relative abundance of the main bacterial genera and the related ARGs increased to the level equal to that in pipelines biofilm with no disinfection. Therefore, NH3-N reduced the ARGs removal efficiency of chlorine disinfection. It is necessary to take measures to improve the removal rate of NH3-N and ARGs for preventing their risks in drinking water.

Corroded iron pipe inhibits microbial-mediated Mn(II) oxidation and MnOx accumulation compared to PVC pipe.

MnOx deposits in distribution pipes can cause severe discoloration problems in drinking water. However, the impact of pipe materials on Mn(II) oxidation and MnOx accumulation remains unclear. This study investigated microbial-mediated Mn(II) oxidation and deposit formation through 300-day pipe loop experiments with corroded galvanized steel pipes (DN100) and new polyvinyl chloride (PVC) pipes (DN100). The results showed that influent Mn(II) was entirely oxidized within 48 h in the PVC pipes with biofilms in the absence of chlorine, while most influent Mn(II) remained unoxidized in the iron pipes. Dissolved oxygen (DO) monitoring showed that the DO in the PVC pipes was consistently higher than 8.0 mg/L, but that in the iron pipes dropped to 6.5 mg/L. Microbial analysis revealed that the abundance of potential Mn(II)-oxidizing bacteria in the low-DO iron pipes was less than that in the PVC pipes. Analysis of the Mn(II) concentration dynamics in different pipes revealed that the early Mn(II) disappearance in the iron pipes was contributed mainly to Mn(II) adsorption by iron corrosion products rather than microbial Mn(II) oxidation. When aeration was performed to increase the DO concentration to 8.0 mg/L in the iron pipes, complete Mn(II) oxidation occurred. This study provides insights into Mn(II) transformation in different pipes and highlights the critical role of DO in microbial Mn(II) oxidation in drinking water pipes.

Transformation of Al Species on Carbon Surfaces: Effects of Al Species and Carbon Surface Oxygen Groups.

Control of residual Al is critical, owing to its high tendency to accumulate in drinking water distribution systems and its potential risks to human health. Herein, the effects of surface properties of activated carbon (AC) on intercepting different Al species (including monomeric Al and polymeric Al species-Al13) are evaluated. The results showed that Al in the form of monomers was considerably adsorbed by AC; whereas Al in the form of polymeric Al13 was held to a much lower degree by AC, and the effluent Al concentration was even higher than that without AC. By comparing virgin AC and hydrogen thermal treated AC, the surface oxygen functional groups on the AC were proposed to play a critical role in the transformation of Al species. The oxygen functional groups on the AC surface can directly form complexes with monomeric Al, thereby inducing the binding of monomeric Al on the AC surface. However, the AC surface oxygen groups could not bind to polymeric Al13, and the interaction between AC surface oxygen groups and polymeric Al13 partially transforms Al13 into monomeric Al species, which inhibited the self-aggregation of Al13. This study aims to provide new insights into the control of residual Al in water treatment plants to ensure drinking water safety.

The interaction between extracellular polymeric substances and corrosion products in pipes shaped different bacterial communities and the effects of micropollutants.

There are growing concerns over the effects of micropollutants on biofilms formation and antibiotic resistance gene (ARGs) transmission in drinking water distribution pipes. However, there was no reports about the influence of the interaction between extracellular polymeric substances (EPS) and corrosion products on biofilms formation. Our results indicated that the abundance of quorum sensing (QS)-related genes, polysaccharide and amino acids biosynthesis genes of EPS was 6747-8055 TPM, 2221-2619 TPM, and 1461-1535 TPM in biofilms of cast iron pipes, respectively, which were higher than that of stainless steel pipes. The two-dimensional correlation spectroscopy (2D-COS) analysis of attenuated total reflectance-Fourier transform infrared spectrometry (ATR-FTIR) results indicated that polysaccharide of EPS was more easily adsorbed onto the corrosion products of cast iron pipes. Therefore, more human pathogenic bacteria (HPB) carrying ARGs were formed in biofilms of cast iron pipes. The amide I and amide II components and phosphate moieties of EPS were more susceptible to the corrosion products of stainless steel pipes. Thus, more bacteria genera carrying mobile genetic elements (MGE)-ARG were formed in biofilms of stainless steel pipes due to more abundance of QS-related genes, amino acids biosynthesis genes of EPS and the functional genes related to lipid metabolism. The enrichment of dimethyl phthalate (DMP), perfluorooctanoic acid (PFOA) and sulfadiazine (SUL) in corrosion products induced upregulation of QS and EPS-related genes, which promoted bacteria carrying different ARGs growth in biofilms, inducing more microbial risks.

The perfluoroalkyl substances influenced the distribution of bacterial communities and their functions from source water to tap water.

Perfluoroalkyl substances (PFASs) and antibiotic resistance genes (ARGs) in drinking water are environmental issues that require special attention. The objective of this study was to know the effects of PFASs on microbial communities and their functional genes from source water to tap water. PFASs were detected by mass-labeled internal standards method, and the microbial communities and functional genes were analyzed by metagenomics. Our results indicated that the concentration of total PFASs in the water ranged from 47.7 to 171.4 ng/L, with perfluorobutanoic acid (PFBA) and perfluorooctanoic acid (PFOA) being the dominant types. The PFASs concentration decreased slowly from source to tap water in some months. PFBA, PFOA, perfluorooctane sulfonic acid (PFOS) and perfluorohexanoic acid (PFHxA) influenced the functional genes related to two-component system, bacterial secretion system and flagellar assembly of Aquabacterium, Methylobacterium, and Curvibacter, which contributed significantly to macB and evgS. Therefore, the bacterial communities enhanced adaptation to fluctuating environments by upregulating some functional genes under the PFASs stress, with concomitant changes in the expression of ARGs. Moreover, PFASs also promoted the expression of functional genes associated with human diseases, such as shigellosis and tuberculosis, which increased the risk of human pathogenicity. The bench scale experiment results also suggested that PFOA and PFOS in drinking water can promote the ARGs proliferation and induce microbial risk. Therefore, it is necessary to take measures to prevent the risks caused by PFASs and ARGs in drinking water.

Iron particles lower than 10 µm in drinking water dominate particle catalysis effect on disinfection byproduct formation.

Iron particles could catalyze disinfection by-product (DBP) formation in drinking water distribution systems (DWDS), but the catalytic effects of iron particles considering size effects have not been focused. Here, we first found that fine particles (lower than 10 µm) dominated the particle catalysis effect of the iron particles on the formation of DBPs containing multiple Cl atoms (DBP-3Cl), especially those with aromatic structure and containing multiple N atoms (DBP-3N). The loose deposit particles were filtered through 50 µm (F50), 10 µm (F10) and 1 µm (F10) membranes, and their turbidity values were 231.6, 53.4 and 1.1 NTU, respectively. In mass ratio, F50, F10 and F1 accounted for 84 %, 15 % and 1 % of unfiltered samples. Notably, the lower mass F10 generated more DBP-3Cl and DBP-3N than F50. Metal crystals and natural organic matters showed little difference among different sizes. The high catalytic activity of particles in F10 due to size effect was proved to be the essential mechanism. F1 contained few particles to affect DBP formation. In toxicity evaluation, the toxicity of F10 was even higher than F50. Therefore, fine particles with sizes lower than 10 µm may play a dominate role in the catalytic effect on DBP transformation in DWDS.

Enhanced disinfection byproducts formation by fine iron particles intercepted in household point-of-use facilities.

To cope with the demand for good-quality potable water, household point-of-use (POU) facilities such as polypropylene cotton filters (PCFs) are widely used. However, the behaviors of new and used PCFs under discoloration are unclear. In this study, we found that new PCF did not effectively intercept particles under discoloration within the initial 5 d of inflow. In addition, the particles, especially the fine ones, accumulated in the long-used PCF exacerbated the risks of disinfection byproducts (DBPs) and microbes. The concentrations of trihalomethanes (THMs) and haloacetonitriles (HANs) in the effluent run through the PCF all increased over time; interestingly, all sharply increased after 5 d in accordance with the decrease in effluent iron particles. During this stage, maximum increases rate of 117.89% in THMs and 75.12% in HANs were observed. For haloacetic acids (HAAs), it served as the dominant contaminants, with concentrations approximately 10-fold greater than those of THMs and HANs. The increase showed that used PCFs could exacerbate the risks in DBPs exposure. Adenosine triphosphate (ATP) also showed a similar trend, with a maximum increase from 0.0033 to 0.0055 nmol/mL. Thus, PCFs can act only as pretreatment units and should be replaced after yellow water events. This study offers important guidance for PCF usage in drinking water purification, especially under discoloration.

NO3- Promotes Nitrogen-Containing Disinfection Byproduct Formation in Corroded Iron Drinking Water Pipes.

Nitrogen-containing disinfection byproducts (N-DBPs) are highly toxic DBPs in drinking water. Though, under normal conditions, NO3- could not directly participate in disinfection reactions to generate N-DBPs, here, we first found that NO3- could promote the formation of N-DBPs in corroded iron drinking water pipes. The coexistence of corrosion produced Fe(II) and iron oxides is a critical condition for the transformation of N species; meanwhile, most of the newly generated N-DBPs had aromatic fractions. The Fe-O-C bond formed between iron corrosion products and natural organic matter promoted electron transfer for the N transformation with pyrrolic N as the intermediate N species. Density functional calculation confirmed that the coexistence of Fe(II) and iron oxides effectively reduced the Gibbs free energy for NO3- reduction. ΔG of the key rate-determining step from NO* to NOH* decreased from 1.55 eV on FeOOH to 1.35 eV on Fe(II)+FeOOH. In addition, the large decrease of cell viability of the water samples from 74.3% to 45.4% further confirmed the formation of highly toxic N-DBPs. Thus, in a drinking water distribution system with corroded iron pipes, the low toxic NO3- may increase toxicity risks via N-DBP formation.

Occurrence of metals, phthalate esters, and perfluoroalkyl substances in cellar water and their relationship with bacterial community in rural areas of China.

Water cellars are traditional rainwater harvesting facilities that have been widely used in rural areas of northwest China. However, there are few reports about the water quality and health risk caused by the cellar water, especially phthalate esters (PAEs) and perfluoroalkyl substances (PFASs). This study investigated and assessed the health risks caused by the metals, PAEs, PFASs and bacterial communities in cellar water. The results showed that the turbidity and total number of bacterial colonies ranged from 4.7 to 58.5 NTU and 5-557 CFU/mL, respectively. The turbidity and total number of bacterial colonies were the main water quality problems. Due to high concentration of Tl (0.005-0.171 µg/L), the samples reached a high level of metal pollution. PAEs showed no non-carcinogenic and carcinogenic risk. The perfluorobutanoic acid (PFBA), perfluorobutanesulfonic acid (PFBS), perfluorooctanoic acid (PFOA), and perfluorooctane sulfonate (PFOS) were the main components of PFASs. PFOA and PFOS reached a moderate risk level in many cellar water samples. Moreover, Tl, Pb, As, PFBA and PFBS could change the bacterial community composition and induce the enrichment of bacterial functions related to human diseases. Besides these parameters, dissolved oxygen (DO) also affected the bacterial functions related to human diseases. Therefore, more attention should be paid to turbidity, DO, Tl, Pb, As, PFOA, PFOS, PFBA and PFBS in the cellar water. These results are meaningful for the water quality guarantee and health protection in rural areas of China.

Phthalate acid esters promoted the enrichment of chlorine dioxide-resistant bacteria and their functions related to human diseases in rural polyvinyl chloride distribution pipes.

Polyvinyl chloride (PVC) pipes are widely used as drinking water distribution pipes in rural areas of China. However, whether phthalate acid esters (PAEs) released from PVC pipes will affect tap water quality is still unknown. The influence of released PAEs on the water quality was analysed in this study, especially after ClO2 disinfection. The results indicated that ClO2 disinfection could control the growth of total coliforms and heterotrophic bacteria (HPC). However, when the ClO2 residual decreased to below 0.10 mg/L, HPC and opportunistic pathogens, including Mycobacterium avium and Pseudomonas aeruginosa, increased significantly. In addition, after ClO2 disinfection, PAEs concentrations increased from 10.6-22.2 µg/L to 21.2-58.8 µg/L in different sampling cites. Linear discriminant analysis (LDA) effect size (LEfSe) and statistical analysis of metagenomic profiles (Stamp) showed that ClO2 disinfection induced the enrichment of Pseudomonas, Bradyrhizobium, and Mycobacterium and functions related to human diseases, such as pathogenic Escherichia coli infection, shigellosis, Staphylococcus aureus infection, and Vibrio cholerae infection. The released PAEs not only promoted the growth of these ClO2-resistant bacterial genera but also enhanced their functions related to human diseases. Moreover, these PAEs also induced the enrichment of other bacterial genera, such as Blastomonas, Dechloromonas, and Kocuria, and their functions, such as chronic myeloid leukaemia, African trypanosomiasis, leishmaniasis, hepatitis C and human T-cell leukaemia virus 1 infection. The released PAEs enhanced the microbial risk of the drinking water. These results are meaningful for guaranteeing water quality in rural areas of China.

Efficient Mn(II) removal by biological granular activated carbon filtration.

Sufficient and sustainable manganese(II) removal is a challenging task to prevent Mn-related drinking water discoloration problems. This study investigated Mn(II) removal by granular activated carbon (GAC) filtration under various conditions. The results showed that biological GAC filter columns could reduce Mn(II) from 400 µg/L to 10 µg/L after a short ripening period, while sand filter columns did not show evident Mn(II) removal function. Water quality changes, pretreatment with NaClO and chemogenic MnOx coating on GAC media surface did not influence the Mn(II) removal capacity of GAC filter columns. 16S rRNA gene sequencing showed that the abundance of potential Mn(II)-oxidizing bacteria in the GAC media was similar to that in the sand media. However, qPCR results indicated that GAC media colonized dramatically more biomass than sand media, resulting in highly effective Mn(II) removal by GAC filter columns. Under chlorinated conditions, GAC filtration underperformed sand filtration in Mn(II) removal, although activated carbon has been reported to be capable of catalyzing Mn(II) oxidation by chlorine. Fast chlorine decay in GAC filter columns made it hard to sustain chemical Mn(II) oxidation and thus led to less Mn(II) removal. This study highlighted the advantage of biological GAC filtration over sand filtration in Mn(II) removal.

Suppression of performance of activated carbon filter due to residual aluminum accumulation.

Extending the lifetime of granular activated carbon (GAC) filters with no significant loss in their effectiveness is a considerable challenge for drinking water supply utilities. However, the effects of residual Al from coagulants on GAC performance are rarely considered. Herein, in-service GAC samples obtained from full-scale water treatment plants were investigated to evaluate the amount of accumulated Al. Although the Al concentration in water was two to three times lower than the Ca concentration, Al exhibited considerable accumulation (second to Ca accumulation) in in-service GAC samples (0.68-8.63 mg g-1). Surface characterization results indicated that Al accumulation could have been caused by the co-precipitation of Al with Ca and Si to form Ca4Al2Si3O10·H2O and Ca4Al6O12SO4, self-precipitation or complexion with -OH/-COOH on the GAC or biofilm surfaces. Correlation analysis of the accumulated Al and GAC properties implied that Al accumulation considerably reduced the surface area of GAC by ∼30%. Lab simulation experiments indicated that the removal of dissolved organic matter was reduced by 6-10% when additional Al was loaded. In addition, results showed that the residual Al (up to 200 µg L-1) considerably affected the extracellular polymeric substance component and microorganism community structure. In summary, strict control of residual Al is beneficial for maintaining the efficacies of GAC and biologically activated carbon.

Perfluorooctanoic Acid (PFOA) Incorporated into Iron Particles Promoted the Formation of Disinfection Byproducts under Drinking Water Conditions.

Perfluorooctanoic acid (PFOA) is an emerging persistent organic pollutant that is frequently detected throughout the drinking water supply system. Here, we first found that PFOA could significantly increase the formation of disinfection byproducts (DBPs) in unlined iron pipes (UIPs) during the distribution process. The increased DBPs were not due to the reaction of PFOA itself with free chlorine, but the in situ formed Fe-PFOA complex played a key role. Notably, PFOA could enhance iron release from UIPs and was greatly incorporated into the iron particles to form Fe-PFOA complex. The •OH generated by the Fe-PFOA heterogeneous reaction could break large dissolved organic matter into small molecules that had higher reactivity with chlorine. In addition, DBP precursors with more aromatic structures were favorable for forming strong Fe-π interactions with Fe-PFOA complex, resulting in more •OH for the formation of aromatic DBPs. The cytotoxicity test showed that the viability of cells exposed to DBPs from UIPs with 100 ng/L PFOA was 46.9%, while that without PFOA was 67.91%. Overall, this study provided a new perspective on the risk of PFOA, with a focus not on PFOA itself but on its potential to promote DBP-associated toxicity in iron-based drinking water distribution pipes.

Efficiency and mechanism of micro- and nano-plastic removal with polymeric Al-Fe bimetallic coagulants: Role of Fe addition.

The occurrence of microplastics (MPs) and even nanoplastics (NPs) in tap water has raised considerable attention. As a pre-treatment and also the most important process in drinking water treatment plants, coagulation has been widely studied to remove MPs, but few studies focused on the removal pattern and mechanism of NPs, especially no study paid attention to the coagulation enhanced by prehydrolysed Al-Fe bimetallic coagulants. Therefore, in this study, polymeric species and coagulation behaviour of MPs and NPs influenced by Fe fraction in polymeric Al-Fe coagulants were investigated. Special attention was given to the residual Al and the floc formation mechanism. The results showed that asynchronous hydrolysis of Al and Fe sharply decreases the polymeric species in coagulants and that the increase of Fe proportion changes the sulfate sedimentation morphology from dendritic to layered structures. Fe weakened the electrostatic neutralization effect and inhibited the removal of NPs but enhanced that of MPs. Compared with monomeric coagulants, the residual Al decreased by 17.4 % and 53.2 % in the MP and NP systems (p < 0.01), respectively. With no new bonds detected in flocs, the interaction between micro/nanoplastics and Al/Fe was merely electrostatic adsorption. According to the mechanism analysis, sweep flocculation and electrostatic neutralization were the dominant removal pathways of MPs and NPs, respectively. This work provides a better coagulant option for removing micro/nanoplastics and minimizing Al residue, which has promising potential for application in water purification.

Three-dimensional reduced graphene reinforced cement with enhanced safety and durability for drinking water distribution applications: Long-term experimental and theoretical study.

Cement mortar lining (CML) is commonly used for iron pipe internal corrosion inhibition in drinking water distribution system (DWDS), however, the corrosion of CML itself is still a problem, particularly under soft water conditions. In this study, both long-term experimental study and theoretical studies were conducted to evaluate the effects of graphene oxide (GO) and three-dimensional reduced graphene oxide (3D-rGO) as additives on the stability of CML and the corresponding water quality. Results showed that during a 182-day leaching experiment, the 3D-rGO modified cement had a higher ability to inhibit the cement constituent leaching than GO modified and original cements. Structural characterization indicated that the addition of 3D-rGO could slightly promote the degree of calcium hydroxide crystallization in CML. Molecular dynamics simulation demonstrated that the 3D-rGO nanosheets strengthened the tensile strain of the cement and restricted the movement of calcium ions by forming strong bonds with the calcium-silicate-hydrate gel network. In addition, compared with GO modified cement and original cement, the 3D-rGO modified cement could somewhat reduce the disinfection by-products formation and the microbial richness in drinking water. Thus, the reinforcement of cement by 3D-rGO could enhance the safety and durability of CML iron pipes in DWDS.

Effects of electrostatic neutralization of Keggin Fe13 on the removal of micro and nano plastic.

The successful preparation and identification of Keggin-structure Fe13 clusters in recent years further enriched the potential application scenarios of ferric coagulants. Comparing the coagulation efficiencies and mechanisms of Fe13 in the removal of nano/microplastics with conventional polymeric Al13 and monomeric Al/Fe, this work aimed to elucidate the coagulation behaviour of Fe13 compared with the traditional mono ferric coagulant, which has the coagulation applied bottleneck of quick and violet hydrolysis. The results showed that Fe13 has a similar electrostatic neutralization potential to Al13, which could keep a positively charged species, especially in acid conditions. The Fe13 species has a selective removal potential toward the microplastics with a polar functional group like ester. Moreover, Fe13 could hydrolyze to form active sol-gel hydroxides in neutral and alkalinity conditions, which is like the behaviour of traditional monomeric Fe coagulants but seldom restabilization. The electrostatic neutralization of Fe13 could enhance the removal of nano plastic from - 25-75% compared with monomeric Fe at pH 4. The higher floc density as a monomeric Fe coagulant and better electrostatic neutralization potential of Keggin Fe13 posed a good prospect for Fe13 to replace the monomeric Fe coagulants in conventional coagulation.